Skip to main navigation menu Skip to main content Skip to site footer

Articles

Vol. 2 No. 2 (2015)

Chemical Composition Control of Evaporated Cu2ZnSnS4 Solar Cells

DOI
https://doi.org/10.15377/2410-2199.2015.02.02.2
Submitted
September 12, 2015
Published
2021-11-26

Abstract

This paper focuses on chemical composition issue of evaporated Cu2ZnSnS4 (CZTS) absorber and potential solutions to it. The chemical composition of the CZTS absorber was estimated by energy dispersive spectroscopy (EDS) and a solution-based Inductively Coupled Plasma Mass Spectroscopy (ICPMS). It discloses a chemical non-uniformity issue spatially on even the same sample and confirms Sn loss issue. It also reveals that substrate option affects composition control.

References

  1. Peter LM. Towards sustainable photovoltaics: the search for new materials. Philosophical Transactions of the Royal Society of London A: Mathematical, Physical and Engineering Sciences 2011; 369(1942): 1840-56. http://dx.doi.org/10.1098/rsta.2010.0348
  2. Green MA, Emery K, Hishikawa Y, Warta W, Dunlop ED. Solar cell efficiency tables (version 43). Progress in Photovoltaics 2014; 22(1): 1-9. http://dx.doi.org/10.1002/pip.2452
  3. B.A. Schubert IMK, S. Cinque, H.W. Schock, G. Meran, editor An economic approach to evaluate the range of coverage of indium and its impact on indium based thin-film solar cells—recent results of Cu2ZnSnS4. 23rd EU-PVSEC; 2008; Valencia.
  4. Schubert B-A, Marsen B, Cinque S, Unold T, Klenk R, Schorr S, et al. Cu2ZnSnS4 thin film solar cells by fast coevaporation. Progress in Photovoltaics: Research and Applications 2011; 19(1): 93-6. http://dx.doi.org/10.1002/pip.976
  5. Mitzi DB, Gunawan O, Todorov TK, Wang K and Guha S. The path towards a high-performance solution-processed kesterite solar cell. Solar Energy Materials and Solar Cells 2011; 95(6): 1421-36. http://dx.doi.org/10.1016/j.solmat.2010.11.028
  6. Chopra KL, Paulson PD and Dutta V. Thin-film solar cells: an overview. Progress in Photovoltaics: Research and Applications 2004; 12(2-3): 69-92. http://dx.doi.org/10.1002/pip.541
  7. Chen S, Gong XG, Walsh A and Wei S-H. Defect physics of the kesterite thin-film solar cell absorber Cu2ZnSnS4. Applied Physics Letters 2010; 96(2): 021902. http://dx.doi.org/10.1063/1.3275796
  8. Yan C, Chen J, Liu F, Song N, Cui H, Ng BK, et al. Kesterite Cu2ZnSnS4 solar cell from sputtered Zn/(Cu and amp; Sn) metal stack precursors. Journal of Alloys and Compounds 2014; 610: 486-91. http://dx.doi.org/10.1016/j.jallcom.2014.05.004
  9. Weber A, Mainz R and Schock HW. On the Sn loss from thin films of the material system Cu–Zn–Sn–S in high vacuum. Journal of Applied Physics 2010; 107(1): 013516. http://dx.doi.org/10.1063/1.3273495